The impact of the alkali cation on the mechanism of the electro-oxidation of ethylene glycol on Pt.

نویسندگان

  • Elton Sitta
  • Bruno C Batista
  • Hamilton Varela
چکیده

By means of in situ IR spectroscopy we investigate the effect of dissolved alkali cations on the electro-oxidation of ethylene glycol on platinum in alkaline media. The results revealed that the increase in the oxidation currents (Li(+) < Na(+) < K(+)) is reflected in the increase in the ratio between carbonate and oxalate produced.

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عنوان ژورنال:
  • Chemical communications

دوره 47 13  شماره 

صفحات  -

تاریخ انتشار 2011